Edward I. Solomon
Publication Details
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Oxygen binding of water-soluble cobalt porphyrins in aqueous solution.
Inorg Chem. 2005; (26): 9628-30
Water-soluble cobalt porphyrin 1Co and imidazole ligand 2 were synthesized. 1Co binds dioxygen in the presence of imidazole ligand 2 in aqueous solution. The formation of the oxygen adduct 2-1Co(O(2)) was studied using UV-vis and EPR spectroscopy. The impact of pH on the kinetic stability of the oxygen adduct was examined.
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