Paul Wender
Publication Details
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Apoptolidins E and F, new glycosylated macrolactones isolated from Nocardiopsis sp.
Org Lett. 2009; (23): 5474-7
Two new glycosylated macrolactones, apoptolidins E (5) and F (6), were isolated from fermentation of the actinomycete Nocardiopsis sp. and their structures assigned. Lacking the C16 and C20 oxygens of apoptolidin A (1), these macrolides are also the first members of this family to display a 4-O-methyl-l-rhamnose at C9 rather than a 6-deoxy-4-O-methyl-l-glucose.
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